Write the chemical equation representing the reaction of ethanol with an acidified solution of potassium dichromate.
Answer
631.5k+ views
Hint:If we look at ethanol, we can say that it is derived from the parent molecule ethane, a hydrocarbon having two carbons. And by looking at the suffix (-ol) of Ethanol we can say that it is alcohol. Potassium dichromate (${{\text{K}}_{\text{2}}}{\text{C}}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}$) is an oxidizing agent that has been acidified by an acid.
Complete step-by-step answer:The for us to write the chemical reaction, let’s look at the reactant first,
1. Ethanol (${\text{C}}{{\text{H}}_3} - {\text{C}}{{\text{H}}_2} - {\text{OH}}$)
2. ${{\text{K}}_{\text{2}}}{\text{C}}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}$ and ${{\text{H}}^{\text{ + }}}$ from any acid.
Now, we know that potassium dichromate is an oxidizing agent, therefore it will oxidize the ethanol,and we also know that primary alcohol will oxidize to give the corresponding aldehyde, and secondary alcohol will oxidize to the corresponding ketone.
Let’s get to our chemical equation now, since Ethanol is the primary alcohol it will oxidize to ethanal. Hence, the required reaction can be written as:
$C{H_3} - \mathop C\limits^{\mathop |\limits^{OH} } - C{H_3} \to C{H_3} - \mathop C\limits^{\mathop {||}\limits^O } - C{H_3}$
Additional information:A primary alcohol has the $\alpha $ carbon and is bonded with only one-carbon group. Secondary alcohol has $\alpha $ a carbon bonded with 2 carbons. And tertiary alcohols have the $\alpha $ carbon bonded with 3-carbon groups.
Let’s see a reaction of secondary alcohol undergoing oxidation with the same reagents, and the reaction can be written as:
${\text{C}}{{\text{H}}_{\text{3}}} - \mathop {\text{C}}\limits^{\mathop {\text{|}}\limits^{{\text{OH}}} } - {\text{C}}{{\text{H}}_{\text{3}}} \to {\text{C}}{{\text{H}}_{\text{3}}} - \mathop {\text{C}}\limits^{\mathop {{\text{||}}}\limits^{\text{O}} } - {\text{C}}{{\text{H}}_{\text{3}}}$
Note: Tertiary alcohols do not undergo oxidation. And if we use a strong oxidizing agent like potassium permanganate (${\text{KMn}}{{\text{O}}_4}$), both the primary alcohols and secondary alcohols will directly get oxidized to the corresponding carboxylic acid.
Complete step-by-step answer:The for us to write the chemical reaction, let’s look at the reactant first,
1. Ethanol (${\text{C}}{{\text{H}}_3} - {\text{C}}{{\text{H}}_2} - {\text{OH}}$)
2. ${{\text{K}}_{\text{2}}}{\text{C}}{{\text{r}}_{\text{2}}}{{\text{O}}_{\text{7}}}$ and ${{\text{H}}^{\text{ + }}}$ from any acid.
Now, we know that potassium dichromate is an oxidizing agent, therefore it will oxidize the ethanol,and we also know that primary alcohol will oxidize to give the corresponding aldehyde, and secondary alcohol will oxidize to the corresponding ketone.
Let’s get to our chemical equation now, since Ethanol is the primary alcohol it will oxidize to ethanal. Hence, the required reaction can be written as:
$C{H_3} - \mathop C\limits^{\mathop |\limits^{OH} } - C{H_3} \to C{H_3} - \mathop C\limits^{\mathop {||}\limits^O } - C{H_3}$
Additional information:A primary alcohol has the $\alpha $ carbon and is bonded with only one-carbon group. Secondary alcohol has $\alpha $ a carbon bonded with 2 carbons. And tertiary alcohols have the $\alpha $ carbon bonded with 3-carbon groups.
Let’s see a reaction of secondary alcohol undergoing oxidation with the same reagents, and the reaction can be written as:
${\text{C}}{{\text{H}}_{\text{3}}} - \mathop {\text{C}}\limits^{\mathop {\text{|}}\limits^{{\text{OH}}} } - {\text{C}}{{\text{H}}_{\text{3}}} \to {\text{C}}{{\text{H}}_{\text{3}}} - \mathop {\text{C}}\limits^{\mathop {{\text{||}}}\limits^{\text{O}} } - {\text{C}}{{\text{H}}_{\text{3}}}$
Note: Tertiary alcohols do not undergo oxidation. And if we use a strong oxidizing agent like potassium permanganate (${\text{KMn}}{{\text{O}}_4}$), both the primary alcohols and secondary alcohols will directly get oxidized to the corresponding carboxylic acid.
Recently Updated Pages
Which of the following graphs shows the variation of class 12 physics CBSE

Draw a labelled diagram of the human male reproductive class 12 biology CBSE

Describe the experiment to compare the emf of two cells class 12 physics CBSE

What is standard hydrogen electrode

What is conventional current and electric current class 12 physics CBSE

2Bromopentane is treated with an alcoholic KOH solution class 12 chemistry CBSE

Trending doubts
A member of Simon commission later became Prime Minister class 12 social science CBSE

Give one example of a reptile that is viviparous class 12 biology CBSE

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

Suicide bags of cells are aEndoplasmic reticulum bLysosome class 12 biology CBSE

Draw a labelled diagram of a simple AC generator class 12 physics CBSE

Define average value of ac over half a cycle Establish class 12 physics CBSE

