The relation between d-spacing formula and Bragg's equation for a cubic crystal for the first-order reflection is given by the relation: \[{\mathbf{sin}}\;{\mathbf{\theta }} = \dfrac{{\mathbf{\lambda }}}{{{\mathbf{2a}}}}{({{\mathbf{h}}^{\mathbf{2}}} + {{\mathbf{k}}^{\mathbf{2}}} + {{\mathbf{l}}^{\mathbf{2}}})^{\dfrac{{\mathbf{1}}}{{\mathbf{2}}}}}\]
State whether the given statement is true or false.
A.True
B.False
Answer
650.1k+ views
Hint: To answer this question you should recall the concept of spacing in a crystalline solid. Use the formula of Bragg’s equation to find the d-spacing. The meaning of a cubic crystal must also be known
The formula used:
\[{\text{d}} = \dfrac{{\text{a}}}{{\sqrt {{{\mathbf{h}}^{\mathbf{2}}} + {{\mathbf{k}}^{\mathbf{2}}} + {{\mathbf{l}}^{\mathbf{2}}}} }}\;{\text{ }}\;{\text{ }}\;....\left( i \right)\]
where \[a = \] lattice parameter and \[{\text{h,\k,\l}} = \;\] Miller indices and
\[{\text{n}}\lambda = 2{{\text{d}}_{{\text{hkl}}}}\sin \theta \;\;{\text{ }}\;{\text{ }}\;(ii)\]
where \[{{\text{d}}_{{\text{hkl}}}}\] = distance between the atomic layers, \[{\text{n}}\] = an integer, \[\lambda \] = wavelength of the incident X-ray beam and \[\sin \theta \;\] = glancing angle
Complete step by step answer:
We know that for a cubic crystal lattice the value of \[n\] in Bragg’s equation is = 1. Bragg’s law is used to determine the angles of coherent and incoherent scattering from a crystal lattice. The movement of the charged particles resulting from X rays radiates waves which are slightly blurred due to different effects and this phenomenon is known as Rayleigh scattering. This forms the basis of diffraction analysis. The phenomenon of diffraction is the result of wave interference, and this analysis is known as Bragg diffraction.
Substituting the value of equation (i) in (ii), we have:
\[{\mathbf{sin}}\;{\mathbf{\theta }} = \dfrac{{\mathbf{\lambda }}}{{{\mathbf{2a}}}}{({{\mathbf{h}}^{\mathbf{2}}} + {{\mathbf{k}}^{\mathbf{2}}} + {{\mathbf{l}}^{\mathbf{2}}})^{\dfrac{{\mathbf{1}}}{{\mathbf{2}}}}}\].
This matches with the statement given in the question, hence, the given statement is true.
Hence the correct option is option A.
Note:
The value of d-spacing is equal to the distance between planes of atoms that give rise to different diffraction peaks in an interference pattern. In the pattern each peak results from a corresponding d-spacing. The diffractogram can be used to develop a 3D coordinate system to describe the planes of atoms with their direction. The value of d-spacing has the dimensions of length, hence usually reported in Ångstroms.
The formula used:
\[{\text{d}} = \dfrac{{\text{a}}}{{\sqrt {{{\mathbf{h}}^{\mathbf{2}}} + {{\mathbf{k}}^{\mathbf{2}}} + {{\mathbf{l}}^{\mathbf{2}}}} }}\;{\text{ }}\;{\text{ }}\;....\left( i \right)\]
where \[a = \] lattice parameter and \[{\text{h,\k,\l}} = \;\] Miller indices and
\[{\text{n}}\lambda = 2{{\text{d}}_{{\text{hkl}}}}\sin \theta \;\;{\text{ }}\;{\text{ }}\;(ii)\]
where \[{{\text{d}}_{{\text{hkl}}}}\] = distance between the atomic layers, \[{\text{n}}\] = an integer, \[\lambda \] = wavelength of the incident X-ray beam and \[\sin \theta \;\] = glancing angle
Complete step by step answer:
We know that for a cubic crystal lattice the value of \[n\] in Bragg’s equation is = 1. Bragg’s law is used to determine the angles of coherent and incoherent scattering from a crystal lattice. The movement of the charged particles resulting from X rays radiates waves which are slightly blurred due to different effects and this phenomenon is known as Rayleigh scattering. This forms the basis of diffraction analysis. The phenomenon of diffraction is the result of wave interference, and this analysis is known as Bragg diffraction.
Substituting the value of equation (i) in (ii), we have:
\[{\mathbf{sin}}\;{\mathbf{\theta }} = \dfrac{{\mathbf{\lambda }}}{{{\mathbf{2a}}}}{({{\mathbf{h}}^{\mathbf{2}}} + {{\mathbf{k}}^{\mathbf{2}}} + {{\mathbf{l}}^{\mathbf{2}}})^{\dfrac{{\mathbf{1}}}{{\mathbf{2}}}}}\].
This matches with the statement given in the question, hence, the given statement is true.
Hence the correct option is option A.
Note:
The value of d-spacing is equal to the distance between planes of atoms that give rise to different diffraction peaks in an interference pattern. In the pattern each peak results from a corresponding d-spacing. The diffractogram can be used to develop a 3D coordinate system to describe the planes of atoms with their direction. The value of d-spacing has the dimensions of length, hence usually reported in Ångstroms.
Recently Updated Pages
If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

A solution of glucose in water is labelled as 10 dfracwv class 11 chemistry CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

What do you mean by retardation What is its SI uni class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Difference between physical and chemical change class 11 chemistry CBSE

