What is the structural difference between high density polythene (HDP) and low density polythene (LDP)?

Question

Vedantu Content Team · Accepted Answer

Hint: . Polythene is a type of polymer whose monomer is ethene or ethylene. The two polymers have different structures  because the temperature, pressure and catalysts used for their formation are different. Complete answer: Polythene is homopolymer which is formed with only one monomer which is Ethene$(\text{C}{{\text{H}}_{2}}\text{=C}{{\text{H}}_{2}}\text{)}$. It is obtained by a free radical polymerization mechanism.

Polythenes are slightly branched or linear long chain molecules. Polythenes have the ability to harden on cooling and soften on heating, because of which they are called as thermoplastics. There are two types of Polythenes:(1) Low density Polythene   (2) High density PolytheneLet us discuss the differences between the two types of Polythenes.LOW DENSITY POLYTHENEHIGH DENSITY POLYTHENEThe temperature and pressure required for the formation of low density polythene is 350K to 570K and 1000 atmosphere to 2000 atmosphere respectively. The temperature and pressure required for the formation of high density polythene is 333K-343K and 6-7 atmospheres respectively. Catalyst required is a peroxide initiator or traces of dioxygen.Catalysts are triethylaluminium and titanium tetrachloride (Ziegler-Natta catalyst).It has a highly branched structure.It has linear structure, and has high density due to close packing, that is why it is also called linear polymer. Are chemically inert, tough but flexible. Are chemically inert, more tough but hard. Used in insulation of electric wires and in manufacturing of toys and pipes.Used in manufacturing of buckets, bottles and dustbins.Cannot resist high temperature.Can resist high temperatures.Have weaker intermolecular forces.Have stronger intermolecular forces.Note: There is no such structural major difference between low density polythene and high density polythene. As the type of formation, the mechanism of formation is the same and the formula with which it is represented is also the same for both. But the reagents used are different. So, it is easier to see these Polythenes in tabular form. Such complex topics are easily learnt through tables. .

LOW DENSITY POLYTHENE	HIGH DENSITY POLYTHENE
The temperature and pressure required for the formation of low density polythene is 350K to 570K and 1000 atmosphere to 2000 atmosphere respectively.	The temperature and pressure required for the formation of high density polythene is 333K-343K and 6-7 atmospheres respectively.
Catalyst required is a peroxide initiator or traces of dioxygen.	Catalysts are triethylaluminium and titanium tetrachloride (Ziegler-Natta catalyst).
It has a highly branched structure.	It has linear structure, and has high density due to close packing, that is why it is also called linear polymer.
Are chemically inert, tough but flexible.	Are chemically inert, more tough but hard.
Used in insulation of electric wires and in manufacturing of toys and pipes.	Used in manufacturing of buckets, bottles and dustbins.
Cannot resist high temperature.	Can resist high temperatures.
Have weaker intermolecular forces.	Have stronger intermolecular forces.

What is the structural difference between high density polythene (HDP) and low density polythene (LDP)?

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