In a saturated solution of the sparingly soluble strong electrolyte $AgI{O_3}$(Molecular mass = 283) the equilibrium which sets in is
$AgI{O_3}(s) \rightleftharpoons A{g^ + }(aq) + IO_3^ - (aq)$
If the solubility product constant ${K_{sp}}$of $AgI{O_3}$ at a given temperature is 1.0$ \times {10^{ - 8}}$, what is the mass of $AgI{O_3}$ contained in 100 ml of its saturated solution ?
a) 28.3$ \times {10^{ - 2}}$g
b) 2.83$ \times {10^{ - 3}}$g
c) 1.0\[ \times {10^{ - 7}}\]g
d) 1.0$ \times {10^{ - 4}}$g
Answer
643.5k+ views
Hint: The solubility product constant gives us the product of the solubility of all components in a solution. In case of $AgI{O_3}$, it can be given by the formula -
${K_{sp}}$=$[A{g^ + }][IO_3^ - ]$
Complete answer:
First, let us write what is given to us and what we need to find out.
Given :
Solubility product constant (${K_{sp}}$) of $AgI{O_3}$= 1.0$ \times {10^{ - 8}}$
Volume of saturated solution = 100 ml
Molecular mass = 283
To find :
mass of $AgI{O_3}$
We know that ${K_{sp}}$ of solution is given by -
${K_{sp}}$=$[A{g^ + }][IO_3^ - ]$
If we say that ‘s’ is the solubility of electrolyte
So, $[A{g^ + }]$=$[IO_3^ - ]$=$[AgI{O_3}]$= s
Thus, ${K_{sp}}$= (s) (s)
${K_{sp}}$=${s^2}$
${s^2}$= 1.0$ \times {10^{ - 8}}$
‘s’ = 1.0$ \times {10^{ - 4}}$M
So, 1000 ml of solution will have electrolyte = 1.0$ \times {10^{ - 4}}$moles
And we have a solution of 100 ml.
Thus, 100 ml of solution will have electrolyte =1.0$ \times {10^{ - 5}}$moles
We have molar mass = 283 g/mol
So, the mass of electrolyte in 100 ml solution = 1.0$ \times {10^{ - 5}} \times 283$
mass of electrolyte in 100 ml solution = 2.83$ \times {10^{ - 3}}$g
So, this is our answer.
Thus, the correct option is option b.).
Note:
The saturated solution is the one which has dissolved the maximum amount of solute. It can not dissolve more solute. Thus, it has the maximum number of moles of an electrolyte that can be present. While the unsaturated solution is one which can dissolve more solute.
${K_{sp}}$=$[A{g^ + }][IO_3^ - ]$
Complete answer:
First, let us write what is given to us and what we need to find out.
Given :
Solubility product constant (${K_{sp}}$) of $AgI{O_3}$= 1.0$ \times {10^{ - 8}}$
Volume of saturated solution = 100 ml
Molecular mass = 283
To find :
mass of $AgI{O_3}$
We know that ${K_{sp}}$ of solution is given by -
${K_{sp}}$=$[A{g^ + }][IO_3^ - ]$
If we say that ‘s’ is the solubility of electrolyte
So, $[A{g^ + }]$=$[IO_3^ - ]$=$[AgI{O_3}]$= s
Thus, ${K_{sp}}$= (s) (s)
${K_{sp}}$=${s^2}$
${s^2}$= 1.0$ \times {10^{ - 8}}$
‘s’ = 1.0$ \times {10^{ - 4}}$M
So, 1000 ml of solution will have electrolyte = 1.0$ \times {10^{ - 4}}$moles
And we have a solution of 100 ml.
Thus, 100 ml of solution will have electrolyte =1.0$ \times {10^{ - 5}}$moles
We have molar mass = 283 g/mol
So, the mass of electrolyte in 100 ml solution = 1.0$ \times {10^{ - 5}} \times 283$
mass of electrolyte in 100 ml solution = 2.83$ \times {10^{ - 3}}$g
So, this is our answer.
Thus, the correct option is option b.).
Note:
The saturated solution is the one which has dissolved the maximum amount of solute. It can not dissolve more solute. Thus, it has the maximum number of moles of an electrolyte that can be present. While the unsaturated solution is one which can dissolve more solute.
Recently Updated Pages
Difference Between Prokaryotic Cells and Eukaryotic Cells

If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

A car covers the first half distance between two places class 11 physics CBSE

The resultant of two vectors overrightarrow P and overrightarrow class 11 physics CBSE

Find the value of cos 135 class 11 maths CBSE

A mass M is held in place by an applied force F and class 11 physics CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Find the value of the expression given below sin 30circ class 11 maths CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

Bond order ofO2 O2+ O2 and O22 is in order A O2 langle class 11 chemistry CBSE

