What is d orbital occupation in the given compound.
${{K}_{3}}[Co{{({{C}_{2}}{{O}_{4}})}_{3}}]$
Answer
638.4k+ views
Hint: Coordination number is the number of atoms, ions, or molecules that a central atom or ion holds as its nearest neighbours in a complex or coordination compound or in a crystal.
Complete answer:
- Coordination numbers are generally between two and nine. The number of bonds depends on the size, charge, and electron configuration of the metal ion and the ligands.
- Typically, the chemistry of complexes is dominated by interactions between s and p molecular orbitals of the ligands and the d orbitals of the metal ions.
- For molecules and polyatomic ions, the coordination number of an atom is determined by simply counting the other atoms to which it is bonded by either single or multiple bonds.
- An orbital is defined as a region in an atom where there is a high probability of finding an electron.
- The d orbital is a clover shaped due to the electrons being pushed out four times during the rotation when an opposite spin proton aligns gluons with three spin-aligned protons.
- In the question, the central metal ion is Cobalt (Co)
Co has coordination number 6
- The oxidation state can be shown as
$\begin{align}
& x-6=-3 \\
& x=+3 \\
\end{align}$
So, the oxidation state is +3
- Since, oxalate is a strong field ligand, pairing will occur. This will keep the $eg$ orbital empty. Therefore, the complex, ${{K}_{3}}[Co{{({{C}_{2}}{{O}_{4}})}_{3}}]$ is diamagnetic.
- The d orbital occupation will be \[t_{2g}^{6}e_{g}^{0}\]
Note: The d orbitals give transition metals their special properties. In transition metal ions the outermost d orbitals are incompletely filled with electrons so they can easily give and take electrons.
Complete answer:
- Coordination numbers are generally between two and nine. The number of bonds depends on the size, charge, and electron configuration of the metal ion and the ligands.
- Typically, the chemistry of complexes is dominated by interactions between s and p molecular orbitals of the ligands and the d orbitals of the metal ions.
- For molecules and polyatomic ions, the coordination number of an atom is determined by simply counting the other atoms to which it is bonded by either single or multiple bonds.
- An orbital is defined as a region in an atom where there is a high probability of finding an electron.
- The d orbital is a clover shaped due to the electrons being pushed out four times during the rotation when an opposite spin proton aligns gluons with three spin-aligned protons.
- In the question, the central metal ion is Cobalt (Co)
Co has coordination number 6
- The oxidation state can be shown as
$\begin{align}
& x-6=-3 \\
& x=+3 \\
\end{align}$
So, the oxidation state is +3
- Since, oxalate is a strong field ligand, pairing will occur. This will keep the $eg$ orbital empty. Therefore, the complex, ${{K}_{3}}[Co{{({{C}_{2}}{{O}_{4}})}_{3}}]$ is diamagnetic.
- The d orbital occupation will be \[t_{2g}^{6}e_{g}^{0}\]
Note: The d orbitals give transition metals their special properties. In transition metal ions the outermost d orbitals are incompletely filled with electrons so they can easily give and take electrons.
Recently Updated Pages
Which of the following graphs shows the variation of class 12 physics CBSE

Draw a labelled diagram of the human male reproductive class 12 biology CBSE

Describe the experiment to compare the emf of two cells class 12 physics CBSE

What is standard hydrogen electrode

What is conventional current and electric current class 12 physics CBSE

2Bromopentane is treated with an alcoholic KOH solution class 12 chemistry CBSE

Trending doubts
Draw a labelled sketch of the human eye class 12 physics CBSE

Which are the Top 10 Largest Countries of the World?

Differentiate between homogeneous and heterogeneous class 12 chemistry CBSE

Draw ray diagrams each showing i myopic eye and ii class 12 physics CBSE

Which is the correct genotypic ratio of mendel dihybrid class 12 biology CBSE

What is the Full Form of PVC, PET, HDPE, LDPE, PP and PS ?

