Assuming that petrol is octane ($C_8$$H_{18}$) and has density \[\text{ 0}\text{.8 g m}{{\text{L}}^{\text{-1}}}\] ,\[\text{ 1}\text{.425 litre}\] of petrol incomplete combustion will consume:
A).\[\text{ 50 mole of }{{\text{O}}_{\text{2}}}\]
B).\[\text{ 100 mole of }{{\text{O}}_{\text{2}}}\]
C).\[\text{ 125 mole of }{{\text{O}}_{\text{2}}}\]
D).\[\text{ 200 mole of }{{\text{O}}_{\text{2}}}\]
Answer
659.7k+ views
Hint: The hydrocarbons with the molecular formula \[{{\text{C}}_{\text{x}}}{{\text{H}}_{\text{y}}}\] undergoes the complete combustion in presence of an excess of oxygen to produce the \[\text{C}{{\text{O}}_{\text{2}}}\] and \[{{\text{H}}_{\text{2}}}\text{O}\]. Here as the oxygen is supplied in the excess amount the number of moles of product formed will depend on the number of moles of propane undergoing the reaction.
Complete answer:
All hydrocarbons burn more than oxygen to form carbon dioxide and water molecules. The general reaction for the combustion of alkanes is as shown below:
\[{{\text{C}}_{\text{x}}}{{\text{H}}_{\text{y}}}\text{ + }\left( \text{x+}\dfrac{\text{y}}{\text{2}} \right)\text{ }{{\text{O}}_{\text{2}}}\text{ }\to \text{ x C}{{\text{O}}_{\text{2}}}\text{ + }\dfrac{\text{y}}{\text{2}}\text{ }{{\text{H}}_{\text{2}}}\text{O}\]
In the general reaction, the x stands for the number of the carbon atom of alkane and y stands for the number of a hydrogen atom bonded to the carbon.
We are provided with the following data:
The propane $\text{ (}{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}}\text{) }$ undergoes complete combustion.
The density of propane is \[\text{ 0}\text{.8 g m}{{\text{L}}^{\text{-1}}}\]
The volume of petrol that undergoes combustion is\[\text{ 1}\text{.425 litre}\].
Let’s first write down the combustion reaction for the propane using the general reaction. we have,
\[\begin{align}
& {{\text{C}}_{8}}{{\text{H}}_{18}}\text{ + }\left( \text{8+}\dfrac{18}{\text{2}} \right)\text{ }{{\text{O}}_{\text{2}}}\text{ }\to \text{ 8 C}{{\text{O}}_{\text{2}}}\text{ + }\dfrac{18}{\text{2}}\text{ }{{\text{H}}_{\text{2}}}\text{O} \\
& \text{ Or} \\
& \text{ }{{\text{C}}_{8}}{{\text{H}}_{18}}\text{ + }\left( \dfrac{25}{\text{2}} \right)\text{ }{{\text{O}}_{\text{2}}}\text{ }\to \text{ 8 C}{{\text{O}}_{\text{2}}}\text{ + 9 }{{\text{H}}_{\text{2}}}\text{O} \\
\end{align}\]
That is one mole of propane reacts with \[\left( \dfrac{25}{\text{2}} \right)\] the number of moles of oxygen.
The mass of propane can be calculated as:
From $\text{ }\!\!\rho\!\!\text{ = }\dfrac{\text{M}}{\text{V}}\text{ }$ we get, $\text{ M = }\!\!\rho\!\!\text{ }\!\!\times\!\!\text{ V }$
Now substitute the values, we have
$\begin{align}
& \text{ M = }\!\!\rho\!\!\text{ }\!\!\times\!\!\text{ V } \\
& \text{ = ( 0}\text{.8 g m}{{\text{L}}^{\text{-1}}}\text{ ) }\!\!\times\!\!\text{ ( 1}\text{.425 liter )} \\
& \text{ = ( 0}\text{.8 g m}{{\text{L}}^{\text{-1}}}\text{ ) }\!\!\times\!\!\text{ ( 1425 mL )} \\
& \text{ = ( 1140 g )} \\
\end{align}$
Therefore, the mass of propane is $\text{1140 g}$.
Let's calculate the number of moles of propane. We have,
$\begin{align}
& \text{ No of moles of propane = }\dfrac{\text{mass of propane }}{\text{Molecular weight of Propane }}\text{ } \\
& \text{ = }\dfrac{\text{1140 g }}{\text{114 g mo}{{\text{l}}^{\text{-1}}}} \\
& \text{ = 10}\text{.00 mol } \\
\end{align}$
Since the molecular weight of propane is $\text{114 g mo}{{\text{l}}^{\text{-1}}}$.
Now we can say that, if one of the moles of propane reacts with the \[\left( \dfrac{25}{\text{2}} \right)\] moles of oxygen, then $\text{10}\text{.96 mole}$ the propane reacts with ‘X’ number of moles of oxygen.
This can be written as:
$\begin{matrix}
\text{1 mole of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}} & \text{=} & \dfrac{\text{25}}{\text{2}}\text{moles of }{{\text{O}}_{\text{2}}} \\
\text{10}\text{.00 moles of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}}\text{ } & \text{=} & \text{X moles of }{{\text{O}}_{\text{2}}} \\
\end{matrix}\text{ }$
On cross multiplying we get,
\[\begin{align}
& \text{ } \\
& \begin{matrix}
\left( \text{X moles of }{{\text{O}}_{\text{2}}} \right)\text{ }\times \text{ }\left( \text{1 mole of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}} \right) & = & \left( \dfrac{\text{25}}{\text{2}}\text{moles of }{{\text{O}}_{\text{2}}} \right)\text{ }\times \text{ }\left( \text{10}\text{.00 moles of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}}\text{ } \right) \\
\end{matrix} \\
& \\
& \text{Or }\left( \text{X moles of }{{\text{O}}_{\text{2}}} \right)\text{ = }\dfrac{\left( \dfrac{\text{25}}{\text{2}}\text{moles of }{{\text{O}}_{\text{2}}} \right)\text{ }\times \text{ }\left( \text{10}\text{.00 moles of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}}\text{ } \right)}{\left( \text{1 mole of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}} \right)} \\
& \\
& \text{Or }\left( \text{X moles of }{{\text{O}}_{\text{2}}} \right)\text{ = }\left( \text{ 125 moles of }{{\text{O}}_{\text{2}}} \right) \\
\end{align}\]
Thus the number of moles of oxygen reacts when the \[\text{ 1}\text{.425 litre}\] of petrol undergoes the combustion is equal to 125 moles.
Hence, (C) is the correct option.
Note:
- If there is an insufficient supply of oxygen it results in the incomplete combustion of a hydrocarbon. The incomplete combustion generates carbon monoxide as the product instead of carbon dioxide.
- In the case of complete combustion of hydrocarbons, the hydrocarbons are limiting reagents. The number of moles of carbon dioxide produced depends on the number of moles of hydrocarbon undergoing the reaction.
Complete answer:
All hydrocarbons burn more than oxygen to form carbon dioxide and water molecules. The general reaction for the combustion of alkanes is as shown below:
\[{{\text{C}}_{\text{x}}}{{\text{H}}_{\text{y}}}\text{ + }\left( \text{x+}\dfrac{\text{y}}{\text{2}} \right)\text{ }{{\text{O}}_{\text{2}}}\text{ }\to \text{ x C}{{\text{O}}_{\text{2}}}\text{ + }\dfrac{\text{y}}{\text{2}}\text{ }{{\text{H}}_{\text{2}}}\text{O}\]
In the general reaction, the x stands for the number of the carbon atom of alkane and y stands for the number of a hydrogen atom bonded to the carbon.
We are provided with the following data:
The propane $\text{ (}{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}}\text{) }$ undergoes complete combustion.
The density of propane is \[\text{ 0}\text{.8 g m}{{\text{L}}^{\text{-1}}}\]
The volume of petrol that undergoes combustion is\[\text{ 1}\text{.425 litre}\].
Let’s first write down the combustion reaction for the propane using the general reaction. we have,
\[\begin{align}
& {{\text{C}}_{8}}{{\text{H}}_{18}}\text{ + }\left( \text{8+}\dfrac{18}{\text{2}} \right)\text{ }{{\text{O}}_{\text{2}}}\text{ }\to \text{ 8 C}{{\text{O}}_{\text{2}}}\text{ + }\dfrac{18}{\text{2}}\text{ }{{\text{H}}_{\text{2}}}\text{O} \\
& \text{ Or} \\
& \text{ }{{\text{C}}_{8}}{{\text{H}}_{18}}\text{ + }\left( \dfrac{25}{\text{2}} \right)\text{ }{{\text{O}}_{\text{2}}}\text{ }\to \text{ 8 C}{{\text{O}}_{\text{2}}}\text{ + 9 }{{\text{H}}_{\text{2}}}\text{O} \\
\end{align}\]
That is one mole of propane reacts with \[\left( \dfrac{25}{\text{2}} \right)\] the number of moles of oxygen.
The mass of propane can be calculated as:
From $\text{ }\!\!\rho\!\!\text{ = }\dfrac{\text{M}}{\text{V}}\text{ }$ we get, $\text{ M = }\!\!\rho\!\!\text{ }\!\!\times\!\!\text{ V }$
Now substitute the values, we have
$\begin{align}
& \text{ M = }\!\!\rho\!\!\text{ }\!\!\times\!\!\text{ V } \\
& \text{ = ( 0}\text{.8 g m}{{\text{L}}^{\text{-1}}}\text{ ) }\!\!\times\!\!\text{ ( 1}\text{.425 liter )} \\
& \text{ = ( 0}\text{.8 g m}{{\text{L}}^{\text{-1}}}\text{ ) }\!\!\times\!\!\text{ ( 1425 mL )} \\
& \text{ = ( 1140 g )} \\
\end{align}$
Therefore, the mass of propane is $\text{1140 g}$.
Let's calculate the number of moles of propane. We have,
$\begin{align}
& \text{ No of moles of propane = }\dfrac{\text{mass of propane }}{\text{Molecular weight of Propane }}\text{ } \\
& \text{ = }\dfrac{\text{1140 g }}{\text{114 g mo}{{\text{l}}^{\text{-1}}}} \\
& \text{ = 10}\text{.00 mol } \\
\end{align}$
Since the molecular weight of propane is $\text{114 g mo}{{\text{l}}^{\text{-1}}}$.
Now we can say that, if one of the moles of propane reacts with the \[\left( \dfrac{25}{\text{2}} \right)\] moles of oxygen, then $\text{10}\text{.96 mole}$ the propane reacts with ‘X’ number of moles of oxygen.
This can be written as:
$\begin{matrix}
\text{1 mole of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}} & \text{=} & \dfrac{\text{25}}{\text{2}}\text{moles of }{{\text{O}}_{\text{2}}} \\
\text{10}\text{.00 moles of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}}\text{ } & \text{=} & \text{X moles of }{{\text{O}}_{\text{2}}} \\
\end{matrix}\text{ }$
On cross multiplying we get,
\[\begin{align}
& \text{ } \\
& \begin{matrix}
\left( \text{X moles of }{{\text{O}}_{\text{2}}} \right)\text{ }\times \text{ }\left( \text{1 mole of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}} \right) & = & \left( \dfrac{\text{25}}{\text{2}}\text{moles of }{{\text{O}}_{\text{2}}} \right)\text{ }\times \text{ }\left( \text{10}\text{.00 moles of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}}\text{ } \right) \\
\end{matrix} \\
& \\
& \text{Or }\left( \text{X moles of }{{\text{O}}_{\text{2}}} \right)\text{ = }\dfrac{\left( \dfrac{\text{25}}{\text{2}}\text{moles of }{{\text{O}}_{\text{2}}} \right)\text{ }\times \text{ }\left( \text{10}\text{.00 moles of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}}\text{ } \right)}{\left( \text{1 mole of }{{\text{C}}_{\text{8}}}{{\text{H}}_{\text{18}}} \right)} \\
& \\
& \text{Or }\left( \text{X moles of }{{\text{O}}_{\text{2}}} \right)\text{ = }\left( \text{ 125 moles of }{{\text{O}}_{\text{2}}} \right) \\
\end{align}\]
Thus the number of moles of oxygen reacts when the \[\text{ 1}\text{.425 litre}\] of petrol undergoes the combustion is equal to 125 moles.
Hence, (C) is the correct option.
Note:
- If there is an insufficient supply of oxygen it results in the incomplete combustion of a hydrocarbon. The incomplete combustion generates carbon monoxide as the product instead of carbon dioxide.
- In the case of complete combustion of hydrocarbons, the hydrocarbons are limiting reagents. The number of moles of carbon dioxide produced depends on the number of moles of hydrocarbon undergoing the reaction.
Recently Updated Pages
Write structures of the following compounds i 2 Chloro3methylpentane class 11 chemistry CBSE

What is BLO What is the full form of BLO class 8 social science CBSE

Explain the Treaty of Vienna of 1815 class 10 social science CBSE

A Paragraph on Pollution in about 100-150 Words

XIX+XXX A 49 B 51 C 55 D 44 class 5 maths CBSE

If x a + bt + ct2 where x is in meters and t is in class 11 physics CBSE

Trending doubts
One Metric ton is equal to kg A 10000 B 1000 C 100 class 11 physics CBSE

Draw a diagram of nephron and explain its structur class 11 biology CBSE

10 examples of friction in our daily life

Proton was discovered by A Thomson B Rutherford C Chadwick class 11 chemistry CBSE

Bond order ofO2 O2+ O2 and O22 is in order A O2 langle class 11 chemistry CBSE

Draw a labelled diagram of the neuron and describe class 11 biology CBSE

