Assertion : MeMgBr should be prepared under perfectly anhydrous conditions.
Reason: Grignard reagent reacts with water.
A. Both Assertion and Reason are correct and Reason is the correct explanation for Assertion
B. Both Assertion and Reason are correct but Reason is not the correct explanation for Assertion
C. Assertion is correct but Reason is incorrect
D. Assertion is incorrect but Reason is correct
Answer
644.1k+ views
Hint: Grignard reagent is used for the preparation of alkanes. It is an organometallic compound that contains carbon-metal bonds. The reactivity of these compounds increase with the percent ionic character of the carbon-metal compound. they react explosively with water and bursts into flame on exposure to air.
Complete step by step answer:
These reactions are carried out in ether solvents as organometallic compounds are strong bases care must be taken to exclude the moisture. Grignard reagent should be prepared under anhydrous conditions, because it is very reactive. It reacts very quickly with any source of proton to give hydrocarbon. Therefore, it is necessary to avoid moisture from Grignard reagents. Let us understand this with the help of a reaction:
$
RX + Mg\xrightarrow{{dryether}}{R^ - }M{g^ + }X \\
{R^ - }M{g^ + }X + {H_2}O \to RH + X - Mg - OH \\
$
MeMgBr should be prepared under perfectly anhydrous conditions. Grignard reagent reacts with water to form alkane and magnesium hydroxy halide. Here Both Assertion and Reason are correct and Reason is the correct explanation for Assertion. Under the following reaction.
$MeBr + Mg\xrightarrow{{E{t_2}O}}MeMgBr$
Alkyl magnesium halide (Grignard reagent)
Grignard reagents have great use in organic synthesis. Not only Grignard reagents are strong bases, they are also powerful nucleophiles and since water is a stronger acid as compared to Grignard reagent it removes its proton. This is also an acid-base reaction.
Note:
A Grignard reagent has a formula RMgX where X is a halogen and R is an alkyl or aryl group. When it reacts with water to produce alkanes. Grignard reagents are sensitive to acidic compounds which is why it is prepared in anhydrous conditions.
Complete step by step answer:
These reactions are carried out in ether solvents as organometallic compounds are strong bases care must be taken to exclude the moisture. Grignard reagent should be prepared under anhydrous conditions, because it is very reactive. It reacts very quickly with any source of proton to give hydrocarbon. Therefore, it is necessary to avoid moisture from Grignard reagents. Let us understand this with the help of a reaction:
$
RX + Mg\xrightarrow{{dryether}}{R^ - }M{g^ + }X \\
{R^ - }M{g^ + }X + {H_2}O \to RH + X - Mg - OH \\
$
MeMgBr should be prepared under perfectly anhydrous conditions. Grignard reagent reacts with water to form alkane and magnesium hydroxy halide. Here Both Assertion and Reason are correct and Reason is the correct explanation for Assertion. Under the following reaction.
$MeBr + Mg\xrightarrow{{E{t_2}O}}MeMgBr$
Alkyl magnesium halide (Grignard reagent)
Grignard reagents have great use in organic synthesis. Not only Grignard reagents are strong bases, they are also powerful nucleophiles and since water is a stronger acid as compared to Grignard reagent it removes its proton. This is also an acid-base reaction.
Note:
A Grignard reagent has a formula RMgX where X is a halogen and R is an alkyl or aryl group. When it reacts with water to produce alkanes. Grignard reagents are sensitive to acidic compounds which is why it is prepared in anhydrous conditions.
Recently Updated Pages
Which of the following graphs shows the variation of class 12 physics CBSE

Draw a labelled diagram of the human male reproductive class 12 biology CBSE

Describe the experiment to compare the emf of two cells class 12 physics CBSE

What is standard hydrogen electrode

What is conventional current and electric current class 12 physics CBSE

2Bromopentane is treated with an alcoholic KOH solution class 12 chemistry CBSE

Trending doubts
Draw a labelled sketch of the human eye class 12 physics CBSE

Which are the Top 10 Largest Countries of the World?

A member of Simon commission later became Prime Minister class 12 social science CBSE

Draw ray diagrams each showing i myopic eye and ii class 12 physics CBSE

Give one example of a reptile that is viviparous class 12 biology CBSE

Which is the correct genotypic ratio of mendel dihybrid class 12 biology CBSE

