A solid AB has NaCl type structure with edge length 580.4pm . The radius of ${A^ + }$ is 100pm . What is the radius (in pm) of ${B^ - }$?
A.190.20
B.540.13
C.525.23
D.78.12
Answer
655.2k+ views
Hint: Sodium chloride is an ionic compound in which sodium and chloride ions are in the ratio of $1:1$.The crystal structure is an ordered array of atoms, ions, or molecules. In the case of NaCl structure, each atom has six nearest neighbors, with octahedral geometry. This arrangement is known as cubic close packing.
Formula used:
${r_c} + {r_a} = \dfrac{a}{2}$
Where, ${r_c} = $radius of cation, ${r_a} = $radius of anion and a$ = $edge length
Complete step by step answer:
Crystal structure is obtained by attaching atoms, groups of atoms or molecules. This structure occurs from the intrinsic nature of the constituent particles to produce symmetric patterns.
NaCl has a cubic unit cell. It is best thought of as a face centered cubic array of anions with an interpreting fcc cation lattice (or vice versa). Its structure is as shown:
Now, in the given question, the edge length is 580.4pm and the radius of cation is 100pm. Let’s find out the radius of anion.
As we know that $NaCl$ has fcc structure, thus according to the formula,
${r_c} + {r_a} = \dfrac{a}{2}$
$100 + {r_a} = \dfrac{{580.4}}{2}$
$ = 290.2pm$
Now, $100 + {r_a} = 290.2pm$
Therefore, ${r_a} = 290.2 - 100$
$ = 190.2pm$
Hence, option A is correct.
Note:
In its aqueous state, NaCl acts as a good conductor of electricity due to the free movement of the ions. It is easily soluble in water and partially soluble in other liquids. It is a major raw material in the industrial manufacturing of various chemicals such as sodium carbonate, sodium hydrogen carbonate etc.
Formula used:
${r_c} + {r_a} = \dfrac{a}{2}$
Where, ${r_c} = $radius of cation, ${r_a} = $radius of anion and a$ = $edge length
Complete step by step answer:
Crystal structure is obtained by attaching atoms, groups of atoms or molecules. This structure occurs from the intrinsic nature of the constituent particles to produce symmetric patterns.
NaCl has a cubic unit cell. It is best thought of as a face centered cubic array of anions with an interpreting fcc cation lattice (or vice versa). Its structure is as shown:
Now, in the given question, the edge length is 580.4pm and the radius of cation is 100pm. Let’s find out the radius of anion.
As we know that $NaCl$ has fcc structure, thus according to the formula,
${r_c} + {r_a} = \dfrac{a}{2}$
$100 + {r_a} = \dfrac{{580.4}}{2}$
$ = 290.2pm$
Now, $100 + {r_a} = 290.2pm$
Therefore, ${r_a} = 290.2 - 100$
$ = 190.2pm$
Hence, option A is correct.
Note:
In its aqueous state, NaCl acts as a good conductor of electricity due to the free movement of the ions. It is easily soluble in water and partially soluble in other liquids. It is a major raw material in the industrial manufacturing of various chemicals such as sodium carbonate, sodium hydrogen carbonate etc.
Recently Updated Pages
Which of the following graphs shows the variation of class 12 physics CBSE

Draw a labelled diagram of the human male reproductive class 12 biology CBSE

Describe the experiment to compare the emf of two cells class 12 physics CBSE

What is standard hydrogen electrode

What is conventional current and electric current class 12 physics CBSE

2Bromopentane is treated with an alcoholic KOH solution class 12 chemistry CBSE

Trending doubts
Draw a labelled sketch of the human eye class 12 physics CBSE

Which are the Top 10 Largest Countries of the World?

A member of Simon commission later became Prime Minister class 12 social science CBSE

Draw ray diagrams each showing i myopic eye and ii class 12 physics CBSE

Give one example of a reptile that is viviparous class 12 biology CBSE

Which is the correct genotypic ratio of mendel dihybrid class 12 biology CBSE

