Why does the mercury cell have a constant cell potential throughout its useful life?
Answer
298.5k+ views
Hint: The cell potential of any cell is maintained by the movement of ions. If the ions are used up completely the cell potential will become zero and stop working.
Complete Step by Step Solution:
Silver \[\left( {Ag} \right)\]is a significantly less reactive metal due to which it does not easily undergo corrosion and does not easily oxidise
.
When Silver comes in contact with air it forms a silver oxide \[\left( {A{g_2}O} \right)\] which when comes in contact with hydrogen sulphide \[\left( {{H_2}S} \right)\], a black silver sulphide \[\left( {A{g_2}S} \right)\] layer is formed on the surface of the silver.
The chemical reaction for the oxidation of silver can be written as
\[2Ag + {O_2} \to A{g_2}O\]
\[A{g_2}O + {H_2}S \to A{g_2}S + {H_2}O\]
Thus, when a black silver sulphide \[\left( {A{g_2}S} \right)\] layer is formed on the surface of the silver we can recognize that silver gets corroded.
The corrosion of silver can be prevented by avoiding exposure to an open place that absorbs moisture and tarnishes silver.
Additional information: If corrosion occurs in iron it is called rusting of iron. When iron is exposed to air and moisture, it forms a layer of iron oxide which is rust. Rust chemically is hydrated iron (lll) oxide \[F{e_2}{O_3}.{H_2}O\].
Rusting of iron can be prevented by galvanization and paintings. Galvanization is the process of applying the coating of zinc which prevents the oxidation of iron.
Note: Generally, in a dry cell the cell constant is maintained due to the movement of ions that after a certain period of time completely use up and stop working.
Complete Step by Step Solution:
Silver \[\left( {Ag} \right)\]is a significantly less reactive metal due to which it does not easily undergo corrosion and does not easily oxidise
.
When Silver comes in contact with air it forms a silver oxide \[\left( {A{g_2}O} \right)\] which when comes in contact with hydrogen sulphide \[\left( {{H_2}S} \right)\], a black silver sulphide \[\left( {A{g_2}S} \right)\] layer is formed on the surface of the silver.
The chemical reaction for the oxidation of silver can be written as
\[2Ag + {O_2} \to A{g_2}O\]
\[A{g_2}O + {H_2}S \to A{g_2}S + {H_2}O\]
Thus, when a black silver sulphide \[\left( {A{g_2}S} \right)\] layer is formed on the surface of the silver we can recognize that silver gets corroded.
The corrosion of silver can be prevented by avoiding exposure to an open place that absorbs moisture and tarnishes silver.
Additional information: If corrosion occurs in iron it is called rusting of iron. When iron is exposed to air and moisture, it forms a layer of iron oxide which is rust. Rust chemically is hydrated iron (lll) oxide \[F{e_2}{O_3}.{H_2}O\].
Rusting of iron can be prevented by galvanization and paintings. Galvanization is the process of applying the coating of zinc which prevents the oxidation of iron.
Note: Generally, in a dry cell the cell constant is maintained due to the movement of ions that after a certain period of time completely use up and stop working.
Recently Updated Pages
Normality of 03 M phosphorus acid H3PO3 is A 05 B 06 class 11 chemistry JEE_Main

A molecule with highest bond energy A Fluorine B Chlorine class 11 chemistry JEE_Main

A 30 solution of H2O2 is marketed as 100 volume hydrogen class 11 chemistry JEE_Main

Covalent compounds generally have low melting and boiling class 11 chemistry JEE_Main

When an acid reacts with a metal carbonate or metal class 11 chemistry JEE_Main

The degeneracy of hydrogen atom that has equal energy class 11 chemistry JEE_Main

Trending doubts
Understanding the Different Types of Solutions in Chemistry

What Are Current and Potential Difference in Electricity?

Understanding Geostationary and Geosynchronous Satellites

Isoelectronic Species: Definition, Examples & Importance

Understanding the Angle of Deviation in a Prism

Degree of Dissociation: Meaning, Formula, Calculation & Uses

Other Pages
JEE Advanced Percentile vs Marks 2026: JEE Main Cutoff, AIR & IIT Admission Guide

JEE Advanced 2026 Notification Out with Exam Date, Registration (Extended), Syllabus and More

Free Radical Substitution and Its Stepwise Mechanism

NCERT Solutions For Class 11 Chemistry Chapter 9 Hydrocarbons - 2026-27 Free PDF Download (Login Required)

Electrochemistry JEE Advanced 2027 Notes - Free PDF Download (Sign-in Required)

Chemistry Question Papers for JEE Main, NEET & Boards (PDFs)

